Answer to Question #89772 in Molecular Physics | Thermodynamics for Shivam Nishad

Question

Using Maxwell relations, derive 1st and 2nd
energy equations. Discuss their physical
significance.

Answer 1

Jefimenko's equations (or the closely related Liénard–Wiechert potentials) are the explicit solution to Maxwell's equations for the electric and magnetic fields created by any given distribution of charges and currents. It assumes specific initial conditions to obtain the so-called "retarded solution", where the only fields present are the ones created by the charges. Jefimenko's equations are not so helpful in situations when the charges and currents are themselves affected by the fields they create.

Numerical methods for differential equations can be used to approximately solve Maxwell's equations when an exact solution is impossible. These methods usually require a computer, and include the finite element method and finite-difference time-domain method. For more details, see Computational electromagnetics.

Maxwell's equations seem overdetermined, in that they involve six unknowns (the three components of E and B) but eight equations (one for each of the two Gauss's laws, three vector components each for Faraday's and Ampere's laws). (The currents and charges are not unknowns, being freely specifiable subject to charge conservation.) This is related to a certain limited kind of redundancy in Maxwell's equations: It can be proven that any system satisfying Faraday's law and Ampere's law automatically also satisfies the two Gauss's laws, as long as the system's initial condition does. This explanation was first introduced by Julius Adams Stratton in 1941. Although it is possible to simply ignore the two Gauss's laws in a numerical algorithm (apart from the initial conditions), the imperfect precision of the calculations can lead to ever-increasing violations of those laws. By introducing dummy variables characterizing these violations, the four equations become not overdetermined after all. The resulting formulation can lead to more accurate algorithms that take all four laws into account.