Answer to Question #109356 in Mechanics | Relativity for Mark Marksman

Question #109356
A 24 g block of ice is cooled to -88°C. It is added to 538 g of water in an 91 g copper calorimeter at a temperature of 29°C. Find the final temperature. The specific heat of copper is 387 J/kg • °C. The latent heat of fusion of water is 3.33 x 10^5 J/kg and its specific heat is 4186 J/kg • °C.
Answer in units of °C.
1
Expert's answer
2020-04-14T09:39:57-0400

Problem:  specific heat of copper is CCu=387Jkg1°C1C_{Cu}=387 J\cdot kg^{-1}\degree C^{-1} ;

specific heat of water is Cw=4186Jkg1°C1C_{w}=4186 J\cdot kg^{-1}\degree C^{-1} ;of ice is Cice=2100Jkg1°C1C_{ice}=2100 J\cdot kg^{-1}\degree C^{-1} ;  The latent heat of fusion of water is λ=3.33105Jkg1\lambda=3.33\cdot 10^5 J\cdot kg^{-1}

Solution: The heat capacity of water seams to be much greater then of the ice, thus we will decide the ice will melt and final temperature of system T>0°CT>0\degree C. Determine the heat capacity wich must be added to block of ice. This consist of three terms. First is the heat capacity to warm ice block to 0°C0\degree C

(1) Qice1=CicemiceΔTiceQ_{ice1}=C_{ice}\cdot m_{ice}\cdot \Delta T_{ice} where mice=0.024kgm_{ice}=0.024 kg and ΔTice=0°C(88)°C=88°C\Delta T_{ice}=0\degree C-(-88)\degree C=88\degree C

Qice1=CicemiceΔTice=21000.02488=4435.2JQ_{ice1}=C_{ice}\cdot m_{ice}\cdot \Delta T_{ice}=2100\cdot 0.024 \cdot 88=4435.2 J

Second is the heat to melt ice block at 0°C0\degree C

(2) Qice2=λmice=3.331050.024=7992JQ_{ice2}=\lambda\cdot m_{ice}=3.33\cdot 10^5 \cdot 0.024=7992 J

Third is to warm water of ice block to final temperature

(3) Qice3=CwmiceTQ_{ice3}=C_{w}\cdot m_{ice}\cdot T

The law of conservation of thermal energy in this case says that all this energy (1)-(3) ice gets from cooled water and copper calorimeter. The water lost the amount of heat 

(4) Qw=Cwmw(TTinit)Q_{w}=C_{w}\cdot m_w\cdot(T- T_{init}) where mw=0.538kgm_w=0.538 kg , and Tinit=29°CT_{init}=29\degree C. The heat of copper changed by

(5) QCu=CCumCu(TTinit)Q_{Cu}=C_{Cu}\cdot m_{Cu}\cdot (T-T_{init}) where mw=0.091kgm_w=0.091 kg

The law of conservation of energy in calorimeter is

(6) Qice1+Qice2+Qice3+Qw+QCu=0Q_{ice1}+Q_{ice2}+Q_{ice3}+Q_{w}+Q_{Cu}=0 Substitute (1)-(5) to (6) we find TT


T=(Cwmw+CCumCu)TinitQice1Qice2Cwmw++CCumCu+Cwmice=(41860.538+3870.091)294435.279922287.3+41860.024==66331.312427.22387.8=22.6°CT=\frac{(C_{w}\cdot m_w+C_{Cu}\cdot m_{Cu})\cdot T_{init} - Q_{ice1}-Q_{ice2}}{C_{w}\cdot m_w++C_{Cu}\cdot m_{Cu}+C_{w}\cdot m_{ice}}=\frac{(4186\cdot 0.538+387\cdot 0.091)\cdot 29- 4435.2-7992}{2287.3+4186\cdot 0.024}=\\{ \\}=\frac{66331.3 -12427.2 }{2387.8}=22.6 \degree C

Answer: The final temperature of system is 22.6°C22.6\degree C


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