Problem: specific heat of copper is CCu=387J⋅kg−1°C−1 ;
specific heat of water is Cw=4186J⋅kg−1°C−1 ;of ice is Cice=2100J⋅kg−1°C−1 ; The latent heat of fusion of water is λ=3.33⋅105J⋅kg−1
Solution: The heat capacity of water seams to be much greater then of the ice, thus we will decide the ice will melt and final temperature of system T>0°C. Determine the heat capacity wich must be added to block of ice. This consist of three terms. First is the heat capacity to warm ice block to 0°C
(1) Qice1=Cice⋅mice⋅ΔTice where mice=0.024kg and ΔTice=0°C−(−88)°C=88°C
Qice1=Cice⋅mice⋅ΔTice=2100⋅0.024⋅88=4435.2J
Second is the heat to melt ice block at 0°C
(2) Qice2=λ⋅mice=3.33⋅105⋅0.024=7992J
Third is to warm water of ice block to final temperature
(3) Qice3=Cw⋅mice⋅T
The law of conservation of thermal energy in this case says that all this energy (1)-(3) ice gets from cooled water and copper calorimeter. The water lost the amount of heat
(4) Qw=Cw⋅mw⋅(T−Tinit) where mw=0.538kg , and Tinit=29°C. The heat of copper changed by
(5) QCu=CCu⋅mCu⋅(T−Tinit) where mw=0.091kg
The law of conservation of energy in calorimeter is
(6) Qice1+Qice2+Qice3+Qw+QCu=0 Substitute (1)-(5) to (6) we find T
T=Cw⋅mw++CCu⋅mCu+Cw⋅mice(Cw⋅mw+CCu⋅mCu)⋅Tinit−Qice1−Qice2=2287.3+4186⋅0.024(4186⋅0.538+387⋅0.091)⋅29−4435.2−7992==2387.866331.3−12427.2=22.6°C
Answer: The final temperature of system is 22.6°C
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