Answer to Question #16503 in Organic Chemistry for Jaz
Acids are less soluble at low pH because the solution already contains H+ ions. According to the law of mass action the addition of more H+ will move the equilibrium to the undissociated form, keeping it less soluble.
At high ph the opposite occurs, the OH- present will remove the H+ ( as H2O) so encouraging more acid to dissolve.Bases are the same but opposite.
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