M(Mg(OH)2) = 24.3 +16*2 + 2 = 58.3
n(Mg(OH)2) = 2.35 / 58.3 = 0.04 mol
Q = Cp(H2O) * (T2 - T1)*m(H2O) = 4179.6 * (36 - 20.5) * 0.25 = 16195.95 J
Hsolution= 16195.95 / 0.04 = 404898.75 J/mol = 404.9 kJ/mol
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