Answer to Question #84781 in Inorganic Chemistry for Vikramaditya

Question #84781
why lanthanide ions do not form complexes with pi bonding ligands
1
Expert's answer
2019-02-04T09:36:45-0500

In lanthanides, the 4f orbitals are well shielded by the larger 5d and 6s orbitals and are deep inside the atom. So f orbitals do not participate in any bonding and complex formation is similar to that of transition metals. However in the actinides, the 5f electrons can form complexes with certain pi bonding.

Solution:

In lanthanides, the 4f orbitals are well shielded by the larger 5d and 6s orbitals and are deep inside the atom. So f orbitals do not participate in any bonding and complex formation is similar to that of transition metals. However in the actinides, the 5f electrons can form complexes with certain pi bonding.

Need a fast expert's response?

Submit order

and get a quick answer at the best price

for any assignment or question with DETAILED EXPLANATIONS!

Comments

No comments. Be the first!

Leave a comment

Ask Your question

LATEST TUTORIALS
New on Blog
APPROVED BY CLIENTS