(i) Find number of moleculs of C9H8O4 
n=Mm 
n(C9H8O4)=180.16molg0.325g=0.00180mol 
N=NA×n 
N(C9H8O4)=6.022×1023mol−1×0.00180mol=1.086×1021molecules 
(ii) find total number of atoms:
As 1 molecule of C9H8O4  contains 9+8+4 = 21 atoms, then 
Ntotal(atoms)=21×N(C9H8O4)=21×1.086×1021=2.281×1022atoms 
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