Answer to Question #190914 in General Chemistry for Kath

Question #190914

Explain why in some cases we obtain less absorption bands than number of mode predicted from the theoretical calculation?


1
Expert's answer
2021-05-10T01:50:27-0400

Because the spacing between energy levels in the anharmonic oscillator decrease with increasing vibrational levels, the hot bands occur at lower frequencies than the fundamentals.


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