Answer to Question #117307 in Physical Chemistry for Ayesha

Question #117307
How the photochemistry of Aniline depends on wavelength?
1
Expert's answer
2020-05-21T13:54:17-0400

Like the -saturated amines, anilines and their N-alkyl derivatives are good electron donors in both the ground and excited states and have been widely used in studies of the behavior of pho-toinduced electron transfer (PET). Although PET could occur between singlet anilines and ground-state acceptors as well as between singlet acceptors and ground-state anilines, most studies employed anilines as ground-state electron donors rather than excited-state donors. This might be associated with the weak long-wavelength absorption and relatively short singlet lifetimes of simple aniline molecules that restrict the choice of ground-state acceptors.


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